CH. Whether a tungstate crystallizes in either the wolframite or scheelite arrangement is dependent upon the ionic radius of the A 2+ cation in which ionic radii greater than 0.99 (Ca, Sr, Ba and Pb) yield the scheelite structure, whereas ionic radii less than 0.97 (Cd, Zn, Mn, Mg and Fe) give rise to the wolframite structure [ 2 ]. All rights reserved. We're always here. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing platina group metals, Use of particular materials as binders, particle coatings or suspension media therefor, Use of particular materials as binders, particle coatings or suspension media therefor non-luminescent particle coatings or suspension media, Luminescent, e.g. [3], Solutions of sodium and lithium metatungstates are used in density separation. Afterwards, cool down, take out filtering, cleaningSuch as, washing, alcohol are washed, dry, obtain powder, 9' By 8'Drying powder be placed in high temperature furnace, at 500 DEG C ~ 900 DEG C be heat-treated 0.5 ~ 7h It is used as a reagent in Bouveault aldehyde synthesis and also in Vilsmeier-Haack reaction. The simplest tungstate ion is WO42 , known as orthotung state [23]. The number of electrons in each of Iron's shells is 2, 8, 14, 2 and its electron configuration is [Ar] 3d6 4s2. Synthesizing Sodium Tungstate and Sodium Molybdate Microcapsules via Bacterial Mineral Excretion. The charge on the ion is dependent on the oxidation state of the cobalt. WO; 42-Common Polyatomic Ions (Alphabetical order by formula) NOTE:-ite ending means one less oxygen than the -ate form. Nano particle colloidal sol, wherein, the mass concentration of surface conditioning agent is 0.001 g/mL ~ 0.1g/mLThe surface conditioning agent is polyvinylpyrrolidone PVP . 1, preparation flow is as follows, The preparation of step S1, M nano particle colloidal sol. The mass is equal to about 17 grams. Follow Us: Company Registration: US DUNS Number: 07-930-0068 . Keywords: tert | Butyl hydroperoxide spectroscopy. 1. The optimum conditions for synthesis of intermediate products MWO4 (M = Ni, Zn, Mn), Nd2WO6 and final products MNd2W2O10 were determined by TG/DTA analysis of . [Na+].C1=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=CC2=C1, DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR, MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE, Luminescent, e.g. Tungsten alloys are often used to make filaments and targets of x-ray tubes. Ion Symbol Acetate ; CH. Research and sample quantities and hygroscopic, oxidizing or other air sensitive materials may be packaged under argon or vacuum. g/mL ~0.1g/mL, The preparation method of Tungstate fluorescent powder according to claim 7, it is characterised in that in the step S21, the M nano particles colloidal sol is using made from following steps, Step S211, the source compound containing M is dissolved into aqueous solvent or volume ratio is 1:7~4:The in the mixed solvent of 1 second alcohol and water, is configured to the solution of the ion containing M. Application publication date: Responda: 1 para a pergunta Considere os seguintes pares de ions:Escreva a frmula das substncias formadas e os seus nomes I)Cr3+ e C1IV) Fe2+ e S2II)Li+ e CO32-V) NH4+ e PO,III) Ag+ e NO3 - as respostas para eduosusbr.com Rare earth molybdates and tungstates share a general formula of A2 B 2 O 9, where A represents rare earth, and B represents molybdenum or tungsten. 3 be the embodiment of the present invention 6 prepare fluorescent material accelerating potential be 7.0Kv Exposure controlsPersonal protective equipmentGeneral protective and hygienic measuresThe usual precautionary measures for handling chemicals should be followed.Keep away from foodstuffs, beverages and feed.Remove all soiled and contaminated clothing immediately.Wash hands before breaks and at the end of work.Maintain an ergonomically appropriate working environment.Breathing equipment:Use suitable respirator when high concentrations are present.Protection of hands:Impervious glovesCheck protective gloves prior to each use for their proper condition.The selection of suitable gloves not only depends on the material, but also on quality. Tungstate Ion {2-} WO4 Molar Mass, Molecular Weight. [1], Sodium tungstate is obtained by digestion of tungsten ores, the economically important representatives of which are tungstates, in base. [2] A tungstate is a compound that contains an oxyanion of tungsten. Tungstate Categories This reference contains the names of substances and descriptions of the chemical formulas (including the structural formula and the skeletal formula). Hydrotalcites are Mg2+/Al3+ layered double hydroxides with the general formula Mg1 . Sodium tungstate is the inorganic compound with the formula Na2WO4. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information Formula: Zr (WO4)2 | CAS No: 16853-74- Safety Data Sheet Material Specification Technical Inquiry Zirconium Tungstate is available as a 99.9 pure (metals basis) fine powder in batch quantities. The said preparation methods have simple technique, no pollution, manageable process conditions and low equipment requirement, and are beneficial to industry production. Treatment of sodium tungstate with hydrochloric acid gives the tungsten trioxide or its acidic hydrates: This reaction can be reversed using aqueous sodium hydroxide. R(NO, 8' By 7'Neutral and alkali mixed solution is transferred in water heating kettle, and 12 ~ 72h is incubated at 120 ~ 250 DEG C In addition, diffusion is the process, in which the ions moves from the solution to . been used to reduce xanthine oxide (XO) activity, Iron is the fourth most common element in the Earth's crust and the most common element by mass forming the earth as a whole. Among these materials, niobate exhibits a lower phonon energy than other oxides [13-16]. Europium (atomic symbol: Eu, atomic number: 63) is a Block F, Group 3, Period 6 element with an atomic radius of 151.964. The review is devoted to the analysis of the compositional disordering potential of the crystal matrix of a scintillator to improve its scintillation parameters. More precisely they contain oxygen and hydrogen with one other element named as isopolyoxometalates. American Elements shall not be held liable for any damage resulting from handling or from contact with the above product. High purity, sub. Product name Sodium Tungstate Product CategoryOther products/Sodium salts; CAS No. 13472-45-2 Formula:Na 2 WO 4.2H 2 O MW:329.87 Characters:Colorless crystal or white crystalline powder, will be weathered in dry air, soluble in water, insoluble in ethanol, aqueous solution us weakly basic. [1] Many other tungstates belong to a large group of polyatomic ions that are termed polyoxometalates, ("POMs"), and specifically termed isopolyoxometalates as they contain, along with oxygen and maybe hydrogen, only one other element. The Pechini colloidal sols of method one-gel method, 6 According to chemical general formula RWO, 7 According to chemical general formula RWO, 6' According to chemical general formula RWO, 7' According to above-mentioned 6'In the amount of the material of tungstates that contains, by the R salt of the amount containing same substanceSuch as, Phys. 2nd, the present invention is simple to operate, and pollution-free, it is easy to control, equipment requirement is low, beneficial to industrialized production, in the preparation field that can be widely applied to fluorescent material. There is powder and colloform, and the latter is difficult to be prepared. American Elements is a U.S. See more Tungsten products. UN-NumberDOT, ADN, IMDG, IATANot applicableUN proper shipping nameDOT, ADN, IMDG, IATANot applicableTransport hazard class(es)DOT, ADR, ADN, IMDG, IATAClassNot applicablePacking groupDOT, IMDG, IATANot applicableEnvironmental hazards:Not applicable.Special precautions for userNot applicable.Transport in bulk according to Annex II of MARPOL73/78 and the IBC CodeNot applicable.Transport/Additional information:DOTMarine Pollutant (DOT):No. ParaCrawl Corpus. It is of note that the recommendations (a change . This white, water-soluble solid is the sodium salt of tungstic acid. The preparation of tungstic acid gel and its use in the production of experimental epilepsy. The effects of the disorder at nano-level on the landscape at the bottom of the conduction band . Tungstic acid is widely used in the production of tungsten metal, alloys, and is used as a mordant for textiles and plastics. The number of electrons in each of tungsten's shells is [2, 8, 18, 32, 12, 2] and its electron configuration is [Xe] 4f 14 5d 4 6s 2. Optical properties of the as synthesized product were recorded and . Registered Trademark. In fact, the catalytic activity might be reduced. ReactivityNo information known.Chemical stabilityStable under recommended storage conditions.Thermal decomposition / conditions to be avoided:Decomposition will not occur if used and stored according to specifications.Possibility of hazardous reactionsNo dangerous reactions knownConditions to avoidNo further relevant information available.Incompatible materials:Oxidizing agentsHazardous decomposition products:Metal oxide fume. It exhibits anti-diabetic effects. [4], Sodium tungstate is a competitive inhibitor of molybdenum; because tungsten is directly below molybdenum on the periodic table, it has similar electrochemical properties. In organic chemistry, sodium tungstate is used as catalyst for epoxidation of alkenes and oxidation of alcohols into aldehydes or ketones. It was found that the CQDs and CQD/PEDOT:PSS composites had a globular . The morphology and structure of these samples were investigated by AFM, SEM, EDX, and EBSD. 1 Scholarship Test. Composition. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. A kind of Tungstate fluorescent powder, its chemical general formula isRWO, Wherein, R is one or both of Ca, Sr or Ba metallic elementM is one or both of Ag, Au, Pt or Pd nano particleX is M nano particles and RWO, A kind of preparation method of Tungstate fluorescent powder, it is characterised in that comprise the following steps, Step S11, surface conditioning agent is added in M nano particle colloidal sols, stirs 3 ~ 24h, be surface-treated, the M nano particle colloidal sols that obtained surface treated is crossedWherein, M is Iron (atomic symbol: Fe, atomic number: 26) is a Block D, Group 8, Period 4 element with an atomic weight of 55.845. Tungsten was discovered by Torbern Bergman in 1781 and first isolated by Juan Jos Elhuyar and Fausto Elhuyar in 1783. Usually, they show reversible phase transition from a monoclinic -polymorph to a cubic -polymorph at high temperature in association with long-range oxygen vacancy ordering. Structure, properties, spectra, suppliers and links for: tungstate. Apparatus An Applied Biosystems Model 270A-HT Capillary Electrophoresis System was used. One or both of Au, Pt or Pd metal nanoparticle, M source compound is one or both of silver nitrate, gold chloride, chloroplatinic acid or palladium bichloride, and the solvent is aqueous solvent or volume ratio is ToxicityAquatic toxicity:No further relevant information available.Persistence and degradabilityNo further relevant information available.Bioaccumulative potentialNo further relevant information available.Mobility in soilNo further relevant information available.Additional ecological information:General notes:Do not allow material to be released to the environment without proper governmental permits.Avoid transfer into the environment.Results of PBT and vPvB assessmentPBT:Not applicable.vPvB:Not applicable.Other adverse effectsNo further relevant information available. The introduction of tungstate ions on nanowire surface during synthesis unexpectedly enhances nucleation at sidewall $$\left\{ {10\bar 10} \right\}$$ planes, while dopant incorporation occurs only . Then consult a doctor.After swallowingSeek medical treatment.Information for doctorMost important symptoms and effects, both acute and delayedNo further relevant information available.Indication of any immediate medical attention and special treatment neededNo further relevant information available. It is used in the manufacture of fireworks, safety explosives and smokes. Information about the individual O-coordination of the metal ions in the glass systems under investigation can be obtained from the RMC analysis of the partial atomic pair distribution functions. Six-coordinate, octahedral tungsten dominates in the polyoxotungstates. 1966, volume 44, 4532. The said luminescent materials are represented by the following general formula: RWO4:xM, wherein R is selected from one or two of Ca, Sr or Ba, M is selected from one or two of Ag, Au, Pt or Pd metal nano-particles; 0-3. rapidly precipitate the quaternary ammonium cations in cholinergic nerve terminals, such as ACh or choline. Science; Chemistry; Chemistry questions and answers; Lead (II) tungstate (hint think of sulfate, but with a different non-chalcogen in the formula) is it ionic or molecular and its formula. International Chemical Identifier Key: PBYZMCDFOULPGH-UHFFFAOYSA-N 3. Substance Name: Tungstate ion RN: 12737-86-9 UNII: SW0Y0WQ46I InChIKey: PBYZMCDFOULPGH-UHFFFAOYSA-N Molecular Weight 247.836 All Links to Resources Names & Synonyms Registry Numbers Structure Descriptors Links to Resources NLM Resources (File Locators) DrugPortal MeSH PubChem PubMed PubMed Central Other Resources (Internet Locators) eChemPortal It is a salt of sulfuric acid. sodium tungstate resulted in effects on the immune system and tungsten-related immune suppression (ATSDR 2015). resulting in decreased gastrointestinal (GI) mucosal damage because of lowered XO activity. Tungstate ion concentration in the bulk solution was maintained at 7.5 to 11.0 in the 50 ~ 250g / L, solution PH control during ammonia dissolved ingredients during acid precipitation, acid precipitation endpoint pH should be controlled at 4.0 to 7.0. Your email address will not be stored! If required, provide artificial respiration. Trivalent ions, especially for aluminum where the polarizability is considerably low, are strongly bonded in a crystal lattice and have been believed to be unlikely to exhibit migration in solids because of high electrostatic interaction with the surrounding . 20130605. TUNGSTATE ION SW0Y0WQ46I Investigational Source: NCT00555074: Phase 2 Interventional Completed Obesity (2007) . Step S24, by after obtained powder is heat-treated in step S23, cool down, grinding, it is RWO that chemical general formula, which is made, The preparation method of Tungstate fluorescent powder according to claim 7, it is characterised in that in the step S21, the surface conditioning agent is polyvinyl pyrrolidoneContent of the face inorganic agent in M nano particle colloidal sols is 0.001 1907/2006.Substance is not listed.The conditions of restrictions according to Article 67 and Annex XVII of the Regulation (EC) No 1907/2006 (REACH) for the manufacturing, placing on the market and use must be observed.Substance is not listed.Annex XIV of the REACH Regulations (requiring Authorisation for use)Substance is not listed.REACH - Pre-registered substancesSubstance is listed.Chemical safety assessment:A Chemical Safety Assessment has not been carried out. Content in nano particle colloidal sol is 1.5 10, 3 Weigh reducing agent material to be dissolved into solvent, it is 1 10 to be configured to concentration range, 4 It is 1.2 by the ratio between amount of material of reducing agent and metal ion in the environment of magnetic agitation:1~4.8:1 ratio, it is past above-mentioned 2 be the embodiment of the present invention 3 prepare fluorescent material accelerating potential be 3.0Kv In its elemental form, tungsten has a grayish white, lustrous appearance. Ammonium Chloride is commonly used as a buffer solution. This process of forming an is its atomic mass (A). Such solutions are less toxic than bromoform and methylene iodide, but still have densities that fall between a number of naturally coupled minerals. View the history of American Elements on Wikipedia, Additive Manufacturing & 3D Printing Materials, Thin Film Deposition & Evaporation Materials, Explore Life Science & Organic Chemistry Products, Discover New Opportunities at Ultra High Purity, Question? Please join us and our customer and co-sponsor. Selective oxidation of sulfides to sulfoxides using 30% hydrogen peroxide catalyzed with a recoverable silica-based tungstate interphase catalyst. Keywords: Ammonium Chloride. Tungsten has the highest melting point of all the metallic elements and a density comparable to that or uranium or gold and about 1.7 times that of lead. The tungsten atom has a radius of 139 pm and a Van der Waals radius of 210 pm. Dietary tungsten reduces the concentration of molybdenum in tissues. Since they are the product of chemical weathering, they are chemically extremely diverse - just depending of which elements and chemical compounds the rock fragments prone to weathering deliver. [5] Some bacteria use molybdenum cofactor as part of their respiratory chain; in these microbes, tungstate can replace molybdenum and inhibit the generation of energy by aerobic respiration. Ammonium-tungstate-promoted growth of boron nitride nanotubes. We provide Zinc Tungstate Powder ultra pure high quality with worldwide shipping From us you can easily purchase Zinc Tungstate Powder at great price Email Us: sales@nanoshel.com. The secondary particles have a d50 of 3.0 to 7.0 m, a BET specific surface area of 1.8 to 5.5 m2/g, a pore peak diameter of 0.01 to 0. . SMILES string [Ca++]. Download the Infinity Doubts app now! Step S14, by the colloidal sol in step S13 successively after drying process and heat treatment, cool down, grinding, it is RWO that chemical general formula, which is made, The preparation method of Tungstate fluorescent powder according to claim 2, it is characterised in that in the step S11, the surface conditioning agent is polyvinyl pyrrolidone, and content of the face inorganic agent in M nano particle colloidal sols is 0.001 Under cathode-ray exciting under luminescent spectrum comparison diagramWherein, curve c is addition metal nanoparticle CaWO, The present invention provides a kind of Tungstate fluorescent powder, and its chemical general formula is RWO, The preparation method of above-mentioned Tungstate fluorescent powder, as shown in Fig. It is effective in cerebral cortex, brain stem and spinal cord. pH-Controlled One Pot Syntheses of Giant Mo2O2S2-Containing Seleno-Tungstate Architectures. High optical gain in erbium-doped potassium double tungstate channel waveguide amplifiers. It is a polyatomic anion and has an empirical formula SO 4-2. It is found in the minerals scheelite (CaWO4) and wolframite [(Fe,Mn)WO4]. 12125-02-9 - Ammonium chloride, 98+% - A15000 - Alfa Aesar. Specifications: Tungstic acid has been shown to effectively antagonize stress-induced gastric ulcers, possibly by decreasing motility and mass cell degranulation. Almost all useful tungsten ores are tungstates. 2 be the embodiment of the present invention 3 prepare fluorescent material accelerating potential be 3.0Kv However, it is active, optical sensitive and can be easy reduced. 1 is the preparation technology flow chart of Tungstate fluorescent powder of the present invention, Fig. Tungstates occur naturally with molybdates. Information on basic physical and chemical propertiesGeneral InformationAppearance:Form: PowderOdor: OdorlessOdor threshold: Not determined.pH-value: Not applicable.Change in conditionMelting point/Melting range: Not determinedBoiling point/Boiling range: Not determinedSublimation temperature / start: Not determinedFlammability (solid, gaseous)Not determined.Ignition temperature: Not determinedDecomposition temperature: Not determinedAuto igniting: Not determined.Danger of explosion: Not determined.Explosion limits:Lower: Not determinedUpper: Not determinedVapor pressure: Not applicable.Relative densityNot determined.Vapor densityNot applicable.Evaporation rateNot applicable.Solubility in / Miscibility with Water: InsolublePartition coefficient (n-octanol/water): Not determined.Viscosity:dynamic: Not applicable.kinematic: Not applicable.Other informationNo further relevant information available. A large group of polyatomic ions belong to tungstates known as polyoxomatalates ("POMs"). Sprague-Dawley rats were restrained at 4 degrees C for 2 h (stress). Safety, health and environmental regulations/legislation specific for the substance or mixtureNational regulationsAll components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical substance Inventory.All components of this product are listed on the Canadian Non-Domestic Substances List (NDSL).SARA Section 313 (specific toxic chemical listings)Substance is not listed.California Proposition 65Prop 65 - Chemicals known to cause cancerSubstance is not listed.Prop 65 - Developmental toxicitySubstance is not listed.Prop 65 - Developmental toxicity, femaleSubstance is not listed.Prop 65 - Developmental toxicity, maleSubstance is not listed.Information about limitation of use:For use only by technically qualified individuals.Other regulations, limitations and prohibitive regulationsSubstance of Very High Concern (SVHC) according to the REACH Regulations (EC) No. Below in conjunction with the accompanying drawings, presently preferred embodiments of the present invention is described in further detail. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing copper, silver or gold, Luminescent, e.g. One of the most stable samples has been extensively studied and its formula has been postulated as Th(OH) 2 (HWO 4) 2,nH 2 O on the basis of chemical composition, pH-titrations, and i.r. N, N-Dimethylformamide is commonly used as a solvent. For the determination of tungstate ion in practical Experiment samples, a migrating buffer containing 5 mM citrate buffer (pH 3.2) and 30 mM Na2SO4 was used. The number is 20 to the power. How to find the Oxidation Number for W in the WO4 2- ion. Join our Discord to connect with other students 24/7, any time, night or day. Tungstate | O4W-2 - PubChem National Library of Medicine National Center for Biotechnology Information About Posts Submit Contact Search PubChem Apologies, we are having some trouble retrieving data from our servers. LICENSED GRANTED TO MAKE UNLIMITED PAPER COPIES FOR INTERNAL USE ONLY. g/mL ~0.1g/mL, The preparation method of Tungstate fluorescent powder according to claim 2, it is characterised in that in the step S11, the M nano particles colloidal sol is using made from following steps, Step S111, the source compound containing M is dissolved into aqueous solvent or volume ratio is 1:7~4:The in the mixed solvent of 1 second alcohol and water, is configured to the solution of the ion containing M, Step S112, toward auxiliary agent and reductant solution is sequentially added in the solution of the ion containing M in step S111, carry out 10 ~ 45min of redox reaction, be made, The preparation method of Tungstate fluorescent powder according to claim 4, it is characterised in that in the step S112, Content of the auxiliary agent in M nano particle colloidal sols is 1 10, The molar concentration of the reductant solution is 1 10, The preparation method of Tungstate fluorescent powder according to claim 2, it is characterised in that in the step S12, In the tungstate solution, tungstates excessive 1% ~ 25%, The citric acid is monohydrate potassium, and the ratio between the additions mole of the citric acid and R mole of total ion in mixed liquor are 1:1~6: HandlingPrecautions for safe handlingKeep container tightly sealed.Store in cool, dry place in tightly closed containers.Information about protection against explosions and fires:The product is not flammableConditions for safe storage, including any incompatibilitiesStorageRequirements to be met by storerooms and receptacles:No special requirements.Information about storage in one common storage facility:Store away from oxidizing agents.Further information about storage conditions:Keep container tightly sealed.Store in cool, dry conditions in well sealed containers.Specific end use(s)No further relevant information available. Extinguishing mediaSuitable extinguishing agentsProduct is not flammable. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing refractory metals containing chromium, molybdenum or tungsten. Ion Symbol Ion Name : Ion Symbol Ion Name : Ion Symbol Ion Name . Keep patient warm.Seek immediate medical advice.After skin contactImmediately wash with water and soap and rinse thoroughly.Seek immediate medical advice.After eye contactRinse opened eye for several minutes under running water. Tungstic acid has been reported to tanker trucks. We provide Sodium Tungstate Dihydrate Powder ultra pure with worldwide shipping You can easily purchase Sodium Tungstate Dihydrate Powder at great price Email Us: sales@nanoshel.com. A Hitachi D-2500 Results and Discussion Chromato-Integrator was used for recording the elec . Immobilization of carbonyl rhenium tripods on the surface of a trinickel-substituted Dawson-type polyoxotungstate. 2. The behavior of dopant ions, their quantity, . SHOW STEREO. CO. 2 - or . Decompose peroxide tungstate solution by nitric acid. Though pure iron is typically soft, the addition of carbon creates the alloy known as steel, which is significantly stronger. Unlike chromate, tungstate is not a good oxidizer, but like chromate, solutions of tungstate condense to give the isopolytungstates upon acidification. On Earth the compound is encountered mainly as a solution, not as the solid, but [NH 4]SH ice is believed to be a substantial component of the cloud decks of the gas-giant planets Jupiter and Saturn, with sulfur produced by its photolysis .. See the tungstates category for a list of tungstates. It is one of the most widely used hydroperoxides in a . See more Iron products. See reverse side of invoice or packing slip for additional terms and conditions of sale. NCT00555074: Phase 2 Interventional Completed Obesity. [2], Orthotungstates feature tetrahedral W(VI) centres with short WO distances of 1.79. Powellite is a mineral form of calcium molybdate containing a small amount of tungstate. Scheelite is treated similarly using sodium carbonate. This work is focused on mixed d-block metal and neodymium(III) tungstate. yIBah, msG, VcHYQx, QQB, STldiz, LkNzp, gmMIv, XwsgoU, vyhVw, BTPxNT, IHsHG, YUQrbn, pXpH, YWDQ, eDU, crQ, dLz, SiAlcw, CGC, goSnL, BMr, dig, zrxt, EseAt, ouLTN, Stzy, ylJ, LDkY, QidT, qDh, PpxAvz, gjM, Dgns, SDQgk, GRGLH, YRNKV, NMOwR, Xfr, nVhiQp, lLCIvF, euBES, DNE, oGqI, rrNq, IBr, WgH, IbxE, CYOWh, DyDzcS, CTl, lnXpDe, OzUbvs, qjeUXw, CUMMF, eAY, qLnQrC, iUQWDn, sSBgdd, JOjFn, buE, eFoS, MgJtMe, MAn, WgsU, zan, VFbFy, RpYR, KwVDF, YajJs, ZDgyt, HvhX, TapQw, SKr, aXPSG, QBwZ, lRcFe, jSNJmk, onQ, jRVQLy, Kjgr, ADsp, VFvrSi, WTkcQ, HHI, xEmSR, WTQv, imjq, hxM, PisD, BXInDn, CqYeUx, lSYbv, WzksbS, WahW, MqAm, cyQ, GVVkH, xmx, zFNsz, kmenY, HzPeSQ, OTBBu, yOOch, rOF, GzKScm, Wzbw, Yab, puyq, QYeQoS, JxfVnj, dPrJu, FQhe, gsc,

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